NEW SURFACE-ACTIVE PETROCOLLECTING AND PETRODISPERSING REAGENT BASED ON STEARIC ACID AND TRYETHYLENETETRAAMINE

Authors

  • I. Zarbaliyeva Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)
  • A. Alimova Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)
  • H. Nabiyeva Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)
  • S. Ahmadbayova Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)
  • A. Mammadov Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)

DOI:

https://doi.org/10.31618/asj.2707-9864.2021.1.54.123

Keywords:

Surface active, adsorption, micellization petrocollecting, petrodispersing, corrosion

Abstract

New surfactant was synthesized from stearic and triethylenetetraamine at room temperature, without utilizing any catalyst or solvent. Structure and composition of the salt was confirmed by using IR-, NMR- and UV- spectroscopies . Surface tension, conductivity measurements were performed on aqueous solutions of new surfactant. Its surface activity and colloidal-chemical parameters such as critical micelle concentration (CMC), surface pressure at CMC (πCMC), surface tension at CMC (γCMC), surface excess (Γmax), concentration required for 20 mN/m reduction of surface tension (C20), Gibbs energies of adsorption and micellization (ΔGad and ΔGmic) were determined. Moreover, corrosion properties and petrocollecting and petrodispersing properties of this salt was determined and maximum values of petrocollecting coefficients was calculated. 

Author Biographies

I. Zarbaliyeva , Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)

Doctor of Chemical Sciences, Associate Professor, Chief Researcher  

A. Alimova , Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)

PhD student

H. Nabiyeva , Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)

PhD student

S. Ahmadbayova , Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)

PhD

A. Mammadov, Institute of Petrochemical Processes (IPCP) of Azerbaijan National Academy of Sciences (ANAS)

PhD student

References

Humbatov H.H., Dashdiyev R.A., Asadov Z.H. et al. Chemical reagents and petroleum production. Baku: Elm, 2001. 448 p.

Humbatov H.H., Dashdiyev R.A. Application of Surfactants for Liquidation of Petroleum Spills. Baku: Elm, 1998, 210 pp. (in Russian)

Zarbaliyeva I.A. Modifications of Undecanoic Acid with Propylene Oxide, Orthophosphoric Acid and Ethanolamines // Chemical Problems, 2017, 2, p. 192-200

Zarbaliyeva I.A. Synthesis and properties of new surface-active reagents based on sunflower, cottonseed oil triglycerides and dietanolamine // News of the Nakhchivan Branch of the Azerbaijan National Academy of Sciences, 2017, No. 4, p. 73–79 Asadov Z.H., Zarbaliyeva I.A., Zargarova S.H.

Propoxylation of aliphatic amines by propylene oxide // Chemical Problems, 2017, №1, p.44-51 Asadov Z. H., Tantawy A. H.,Zarbaliyeva I.A. Synthesis of novel petroleum-collecting and dispersing agents based on oleic acid for cleaning water surface from thin petroleum films/ 13th Ibn Sina International Conference on Pure and Applied Heterocyclic

Chemistry Heterocyclic Chemistry for Sustainable Future, Hurgada, Egypt, 14-17 February, 2015, p. 271

Asadov Z. H., Tantawy A. H., Zarbaliyeva I.A. et al. Synthesis of New Surface-Active Ammonium-Type Complexes Based on Palmitic Acid for Removing Thin Petroleum Films from Water Surface/ The 1st Conference on Science Diplomacy and Developments in Chemistry, 2012 Alexandria, Egypt. p.199.

Asadov Z.H., Tantawy A.H., Zarbaliyeva I.A. et al. Petroleum-Collecting and Dispersing Complexes Based on Oleic acid and Nitrogenous Compounds As Surface-Active Agents for Removing Thin Petroleum Films from Water Surface // Journal of Oleo Science, 2012, V. 61,11, p. 621-630.

Rosen M.J. Surfactants and Interfacial Phenomena, 3rd Edn.NewYork:JohnWiley and Sons, Inc. 2004,444 pp.

Abd El-Lateef H. M., Aliyeva L. I., Abbasov V. M., Ismayilov T. A., Ismayilova X. R. Development of New Eco-Friendly Corrosion Inhibitors Based on Vegetable Oils for Protection from CO2 Corrosion //

Chemistry Journal, 2012, V. 02 (№ 02), p. 37-51) 150(. Abd El-Lateef H. M., Abbasov V. M., Aliyeva L. I., Qasimov E. E., Ismayilov T. I. LPR Corrosion Rate, Weight Loss Measurements and SEM Studies of the Effect of the Some Novel Surfactants as Corrosion Inhibitors for Carbon Steel in CO2 -Saturated 1% NaCl Solutions // Journal of Surfaces and Interfaces of Materials, 2012, V. 1, p.1–11) 148( .

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Published

2021-11-22

Issue

Vol. 1 No. 54 (2021)

Section

Статьи

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